(133)Vapor-Phase Method for the Preparation of Isocyanates. II. Synthesis of Higher Alkyl Isocyanates and Hexamethylenediisocyanate.
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چکیده
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A Convenient Method for the Synthesis of Sterically Hindered Aryl Isocyanates
Several methods have been reported for the syn thesis of isocyanates, most of them involving the use of phosgene: e.g. phosgene and primary amines [1] either in basic [2] or in acidic medium [1]; phosgene and diaryl urea [1]; phosgene and l-alkyl-3-arylsulphonyl urea [3]; or phosgene and sulfinyl amines [4], Isocyanates were further synthesized from olefins or alkyl halides by the use of isocy...
متن کاملThe role of isocyanates in fire toxicity
Isocyanates are a group of low molecular weight, highly reactive compounds with a functional isocyanate group. The main human exposure route is via inhalation of airborne isocyanates, although dermal exposure has also been reported. The inhalation of isocyanates is associated with severely adverse health effects such as asthma, inflammation in the respiratory tract and cancer. During thermal de...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1953
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.56.289